Alignment is an 
Order Grenade.
Its special effect is Coordinated.
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How to Unlock The Legendary Alignment Grenade
Legendary Loot
Ordnance
Overview
How To Unlock
Unlock Location:
- Activate the Warped & Weird Vault Card.
- Earn Points by completing challenges and leveling up.
- Once you have enough points you will be able to purchase the Alignment from the Vault Card.