Scaling the Poisonous Concoction levels with your quiver, you want multiples of 50 when scaling gem levels off your quiver. Example 350 400 450 etc.
You getting this done with Widowhail and using jewels sockets from the tree.
Jewels stat priority: - % increased bonuses gained from equipped quiver till you reach the next break point.
You need +50 spirit you can get this from your body armour and amulet combined. Or just from your body armour.
Amulet annointment is Ancient Aegis
Helm: just get huge Energy shield and resistance
Quiver: Must have +2 projectile skills, crit chance (can get it as an implicit but this is expensive)
EDIT: Since 0.1.1 patch the bow damage not applies to the Poisonous Concoction
Others: Attributes for your gear gems, resistance
Mapping setup:
When you just doing maps you need to switch out Maligaro's Virtuosity to a rare gloves and your rare boots to Corpsewade