You have to build the team around Baicang, and can’t slot him in any team. His options are limited, and to reach his full potential, he prefers a team full of S-Class characters to complement his playstyle
Baicang Full Star Team
Baicang
Daffodill
Sakiri
Jiuyuan
The ideal, best team for Baicang, and best team overall in the bottom half of the Esper Circle, assuming the player can execute combos and quick swap correctly.
The whole team serves as amplification for Scorch and Baicang. Sakiri as an ATK buffer, who also increases enemies’ DoT taken. Daffodill to trigger Scorch with Baicang. Jiuyuan to group enemies, Burst DPS, and proc Hexed to replicate a portion of all Incantation DMG dealt to enemies.
F2P Budget Team
Baicang
Daffodill
Adler
Haniel
You ditch Hexed, DoT amplifier, and a Burst DPS for a shielder, more breaks, more Scorch, and Discord reaction. The team is more comfortable with the shields, to be safer while Baicang drains his own HP.
Such a team is suitable for Beyond the Rail endgame mode, when your other team utilizes all premium supports.
Adler will proc extra Scorch and grant a shield. Haniel's Psyche element enables Nova (with Daffodill) and Discord (with Daffodill + Adler), adding break damage to the team. Daffodill will break Bosses more often. But Baicang deals less personal DPS. A fair trade, considering the investment.